Ernest Solvay
As I'm sure you know, the
Otago Daily Times
recently celebrated its 150th anniversary, and so in this, the
final column of the year, it seems appropriate to look at what
was happening in chemistry in the first year of its
publication, 1861.
The elements rubidium and thallium were both discovered that
year - neither are what one would call particularly useful,
but the latter was often used in rat poison, and was famously
implicated in a veritable orgy of poisonings (46 reported
cases, 10 deaths) in Sydney during 1952-53. Frederick
Hopkins, discoverer of vitamins and future Nobel laureate was
born in 1861, the same year Aleksandr Butlerov presented his
seminal ideas of chemical structure which now underpin all of
chemistry.
However, the big chemical news of 1861 belonged to a
22-year-old Belgian factory worker who had to shelve his
plans to study engineering at university owing to an attack
of pleurisy. His name was Ernest Solvay, and in 1861 he
patented "the industrial manufacture of carbonate of soda by
means of sea salt, ammonia and carbonic acid", a procedure
which soon came to be known as the Solvay process. Carbonate
of soda was, in the past, also called soda ash and washing
soda, but is better known these days to chemists as sodium
carbonate, Na2CO3. It is used extensively in the manufacture
of glass, paper, detergents and soap.
The Solvay process quickly became the method of choice for
the production of sodium carbonate, as it was much cheaper
and far less polluting than the method that preceded it. As a
result, by the end of the 1870s, Solvay had over 20 factories
in France, Germany, England, the United States, Austria and
Russia churning out tonnes of the material. Not surprisingly,
this made Solvay rather rich and, like his near contemporary,
Alfred Nobel, he turned to philanthropy, endowing institutes
of physiology and social science, a school of commerce and a
workman's educational centre at the Free University of
Brussels.
However, Solvay's lasting fame came as a result of his
scientific inquisitiveness - he had a longstanding interest
in both gravitation and the structure of matter, and a
meeting with the soon-to-be Nobel laureate Walther Nernst in
1910 set in course a train of events that led to the
organisation of conferences charged with addressing topical
questions of chemistry and physics. As a result, the first
Solvay conference, whose theme was "The Theory of Radiation
and the Quanta", was held in Brussels in 1911.
And it would have just been another conference were it not
for Solvay's insistence that only the finest scientists of
the day be invited. The list of participants is quite
extraordinary; of the 24 attendees, Einstein, Rutherford,
Curie, Nernst, Planck, Wien, Lorentz, Perrin and Kamerlingh
Onnes were already, or would go on to become, Nobel
laureates. This quality of participants reached its zenith in
the legendary fifth Solvay conference of 1927 on "Electrons
and Photons", where 17 of the 29 attendees were, or would
become, Nobel laureates.
Solvay died in 1922, but Solvay conferences continue to this
day - indeed, the centenary conference was held in October.
Such events are, not surprisingly, by invitation only. I'm
not holding my breath.
And that, dear readers, brings to an end the International
Year of Chemistry. In 2012, we have the International Year of
Sustainable Energy for All, and the International Year of
Co-operatives to look forward to. Oh, and according to the
Mayans, the world is going to end.
• Dr Blackman is an associate professor in the
chemistry department at the University of Otago.
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