She was 77-year-old Judith Mary Egerton, of Dunedin.
Police and St John staff were called to the scene about 6pm.
The road was closed for a time and reopened about 10pm.
Police extended their sympathies to her family and friends.
The Serious Crash Unit investigation is continuing.
Earlier, an 80-year-old woman was hit by a car at the intersection of North Rd and Crown St.
The incident occurred about 3.20pm, a police spokesman said.
The woman had serious injuries and was taken to Dunedin Hospital.
• A man was killed when the car he was driving and a truck collided on the Rakaia Bridge in Canterbury about 2.40pm yesterday. He was Ian Adrian Yee (48), of Christchurch.